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Suzuki, Kaori*; Tsuchimoto, Masanobu*; Aoyagi, Noboru; Watanabe, Masayuki; Nakajima, Kiyohiko*
no journal, ,
Mononuclear Y(III), La(III), Gd(III) complexes ((CH)N[Ln(L)]) with tetradentate Schiff base ligands derived from chiral stilbenediamine were synthesized. The luminescence of these complexes exhibited different in luminescence color between the chiral complexes and the racemic complexes. In this presentation, luminescence properties on the crystalline powder of mononuclear Y(III), La(III), Gd(III) complexes were investigated in detail. It was found out that the different luminescence spectra of crystalline were observed in between chiral and racemic complexes, but the similar luminescence spectra were observed in the ground ones.
Okusa, Masako*; Tsuchimoto, Masanobu*; Watanabe, Masayuki; Nakajima, Kiyohiko*
no journal, ,
Mononuclear Eu(III) complexes with tetradentate schiff base ligands (CH)NH[Eu(L)] (L:3,5Clsalen) exhibits strong red luminescence under ultraviolet light at 360 nm. The derivatives of this complex varies its luminescence in the solid state by the structural change of the ligand or counter cation. In this presentation, luminescence properties of mononuclear europium(III) complex with tetradentate Schiff base ligands and different counter cations such as X=(CH)NH , (CH)N in solutions were investigated.